A novel energy efficient path for nitrogen fixation using a non-thermal arc


Plasma-assisted nitrogen fixation is a promising sustainable and clean alternative to the classical Haber–Bosch process. However, the high energy consumption and low production rate of plasma-assisted nitrogen fixation limit its application.  The researchers from Korea Institute of Machinery and Materials show that the non-thermal (non-equilibrium) enhancement of the arc plasma significantly reduces the energy consumption of nitrogen fixation. The highest energy efficiency with high NO selectivity is observed with a low specific energy input (SEI). However, the highest production rate is reached at a high SEI. The studied process offers high NO selectivity (up to 95%) with low energy consumption (∼48 GJ per tN) at 0.1 kJ L−1 SEI, which is much lower than the previously reported value of plasma-assisted atmospheric nitrogen fixation and is close to that of the Haber–Bosch process.

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